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11.
Back Cover: CH Activation Generates Period‐Shortening Molecules That Target Cryptochrome in the Mammalian Circadian Clock (Angew. Chem. Int. Ed. 24/2015) 下载免费PDF全文
Tsuyoshi Oshima Dr. Iori Yamanaka Dr. Anupriya Kumar Dr. Junichiro Yamaguchi Dr. Taeko Nishiwaki‐Ohkawa Kei Muto Rika Kawamura Dr. Tsuyoshi Hirota Prof. Dr. Kazuhiro Yagita Prof. Dr. Stephan Irle Prof. Dr. Steve A. Kay Prof. Dr. Takashi Yoshimura Prof. Dr. Kenichiro Itami 《Angewandte Chemie (International ed. in English)》2015,54(24):7200-7200
12.
Horinouchi T Nakagawa H Suzuki T Fukuhara K Miyata N 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(17):4809-4813
We report a novel NO donor (RpNO), containing a 2,6-dimethylnitrobenzene moiety for photocontrollable NO release and a rhodamine moiety for targeting to mitochondria. Photorelease of NO from RpNO in aqueous solution was confirmed by means of ESR analysis. Cellular release of NO from RpNO was confirmed with the aid of DAF-FM DA, an NO-specific fluorescence probe. RpNO was colocalized with MitoTracker Green FM, a mitochondrial stain, in HCT116 colon cancer cells and exhibited photodependent cytotoxicity. Our results indicate that RpNO is an effective NO donor for time-controlled, mitochondria-specific NO treatment. 相似文献
13.
The optically active (R)- and (S)-flavanones were prepared by an enzymatically enantioselective hydrolysis of (±)-flavanone oxime O-acylates employing lipases, followed by hydrolysis with acid. 相似文献
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In the present work, a method was developed and optimized aiming at the determination of anatoxin-a in environmental water samples. The method is based on the direct derivatization of the analyte by adding hexylchloroformate in the alkalinized sample (pH = 9.0). The derivatized anatoxin-a was extracted by a solid-phase microextraction (SPME) procedure, submersing a PDMS fiber in an amber vial for 20 min under magnetic stirring. GC-MS was used to identify and quantify the analyte in the SIM mode. Norcocaine was used as internal standard. The following ions were chosen for SIM analyses (quantification ions in italics): anatoxin-a: 191, 164, 293 and norcocaine: 195, 136, 168. The calibration curve showed linearity in the range of 2.5-200 ng/mL and the LOD was 2 ng/mL. This method of SPME and GC-MS analysis can be readily utilized to monitor anatoxin-a for water quality control. 相似文献
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Abdelwareth A. O. Sarhan Mohammed S. Ibrahim Mostafa M. Kamal Kaiko Mitobe Taeko Izumi 《Monatshefte für Chemie / Chemical Monthly》2009,9(11):315-323
Abstract
New ferrocenyl ketones were obtained as precursors of novel π-conjugated ferrocene-dithiafulvalene (Fc-DTF) and π-extended-ferrocenedithia-fulvalenes (π-exFc-DTF) as electron-donor conducting materials from ferrocene by a direct aroylation process using the Friedel–Crafts reaction. Novel Fc-DTF conjugates were synthesized using the Wittig–Horner reaction and their structures were determined. The redox behavior of the ferrocenyl carbonyl compounds Fc-DTF and Fc-π-exDTF was investigated in comparison to the parent ferrocene by means of cyclic voltammetry. A one-electron redox behavior was observed for carbonylferrocenes as one wave potential, while a two-electron process was observed as two oxidation waves for the conjugates. Introduction of electron-withdrawing groups led to increasing E pa values and decreasing ΔE p values. The UV–Vis spectra of some compounds were studied in comparison with ferrocene. The absorption spectra showed a red-shift with a slight increase in the absorption intensities. 相似文献18.
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Taeko Yamazaki 《Mathematical Methods in the Applied Sciences》2009,32(15):1893-1918
We consider a hyperbolic–parabolic singular perturbation problem for a quasilinear hyperbolic equation of Kirchhoff type with dissipation weak in time. The purpose of this paper is to give time‐decay convergence estimates of the difference between the solutions of the hyperbolic equation above and those of the corresponding parabolic equation, together with the unique existence of the global solutions of the hyperbolic equation above. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
20.
Acoustical parameters calculated from impulse responses are often used to evaluate the characteristics of concert halls. Representative parameters are listed in the Annex of ISO 3382 and the methods of calculation and the minimum number of measurement positions are explained in detail. However, a method for selecting measurement positions is not discussed clearly, because there are wide variations in the characteristics of sound fields. This report provides basic data to solve this problem using spatial distribution characteristics of parameters in halls. Three large-scale measurement campaigns were conducted in which impulse responses were measured at 1427, 180, and 511 locations. Relatively large differences in the obtained parameters compared with well-known difference limens suggest that determining the distributions of parameter values is important. Contour maps are therefore used to display the distributions along with mean values. 相似文献